出處: https://blogs.office.com/2013/06/03/opening-workbooks-by-running-separate-instances-of-excel/
one way to start an additional instance of Excel is to press and hold the ALT key, then, without releasing the ALT key, right-click the Excel icon in the Windows taskbar and click the Excel icon above the Unpin option.
Continue holding down the ALT key until you are asked whether you want to start a new instance of Excel.
Click Yes to get a second instance of Excel up and running.
In general, anytime Excel is starting up, holding down the ALT key triggers the above dialog asking about a new instance.
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